As a rule, we work to interpret the data generated in the lab as quantitatively as possible. In our paleoceanographic work, geochemical box models are often used. Through collaboration with researchers GFDL and AOS researchers, we have made some use of more physically realistic ocean/atmosphere models.

Output from the standard case of an ocean model developed by Agatha de Boer and applied by her to study the interaction of ocean ventilation with climate. See de Boer et al.
References
One potential mechanism for lowering atmospheric CO2 during glacial times is an increase in the fraction of the global ocean ventilated by the North Atlantic, which produces deep water with a low concentration of unused nutrients and thus drives the ocean s biological pump to a high efficiency. However, the data indicate that during glacial…
Severely negative 14C anomalies from the mid-depth Pacific and the Arabian Sea have been taken as support for the hypothesized deglacial release of a previously isolated, extremely 14C-deplete deep ocean carbon reservoir. We report box model simulations that cast doubt on both the existence of the hypothesized deep reservoir and its ability to…
In a box model synthesis of Southern Ocean and North Atlantic mechanisms for lowering CO2 during ice ages, the CO2 changes are parsed into their component geochemical causes, including the soft-tissue pump, the carbonate pump, and whole ocean alkalinity. When the mechanisms are applied together, their interactions greatly modify the net CO2…
North Atlantic (NA) deep-water formation and the resulting Atlantic meridional overturning cell is generally regarded as the primary feature of the global overturning circulation and is believed to be a result of the geometry of the continents. Here, instead, the overturning is viewed as a global energy-driven system and the robustness of NA…
A growing number of paleoceanographic observations suggest that the ocean s deep ventilation is stronger in warm climates than in cold climates. Here we use a general ocean circulation model to test the hypothesis that this relation is due to the reduced sensitivity of seawater density to temperature at low mean temperature; that is, at lower…
We have previously argued that the Antarctic and subarctic North Pacific are stratified during ice ages, causing to a large degree the observed low CO2 levels of ice age atmospheres by sequestering respired CO2 in the ocean abyss. Here, we suggest a mechanism for the major deglaciations of the late Pleistocene. The mechanism begins with…
We investigate the response of the 15N/14N of oceanic nitrate to glacial/interglacial changes in the N budget, using a geochemical box model of the oceanic N cycle that includes N2 fixation and denitrification in the sediments and suboxic water column. This model allows us to quantify the isotopic response of different oceanic nitrate pools to…
The low-latitude ocean is strongly stratified by the warmth of its surface water. As a result, the great volume of the deep ocean has easiest access to the atmosphere through the polar surface ocean. In the modern polar ocean during the winter, the vertical distribution of temperature promotes overturning, with colder water over warmer, while…
It is easy to imagine that the terrestrial biosphere sequesters atmospheric carbon dioxide; the form and quantity of the sequestered carbon, living or dead organic matter, are striking. In the ocean, there are no aggregations of biomass comparable to the forests on land. Yet biological productivity in the ocean plays a central role in the…
Using an ocean box model, we have studied the effect of altered circulation on the oceanic distributions of phosphate (PO4-3) and the 13C/12C and 14C/12C of dissolved inorganic carbon to evaluate competing hypotheses for the cause of observed nutrient depletion and 13C enrichment at intermediate depths of the Atlantic during the last ice age…
Twenty years ago, measurements on ice cores showed that the concentration of carbon dioxide in the atmosphere was lower during the ice ages than it is today. As yet, there is no broadly accepted explanation for this difference. Current investigations focus on the ocean s biological pump , the sequestration of carbon in the ocean interior by the…
We investigate the response of the calcite lysocline to changes in the export production of the low-latitude surface ocean (the combined equatorial, tropical, and subtroical regions). We employ different CaCO3 throughput schemes in a time-dependent ocean carbon cycle model to separate the CaCO3 production/iysocline balance from the other…
Temporal variations in the atmospheric concentration of radiocarbon sometimes result in radiocarbon-based age-estimates of biogenic material that do not agree with true calendar age. This problem is particularly severe beyond the limit of the high-resolution radiocarbon calibration based on tree-ring data, which stretches back only to about 11…